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Chemistry
Paper- I : Inorganic
&Physical Chemistry
SYLLABUS
UNIT –I : Chemistry of p-block elements
Group 13: Preparation & structure of Diborane, Borazine
Group 14: Preparation, classification and uses of silicones
Group 15: Preparation & structures of Phosphonitrilic halides {(PNCl2)n
where n=3, 4
Group 16: Oxides and Oxoacids of Sulphur (structures only)
Group 17: Pseudohalogens, Structures of Interhalogen compounds.
1. Chemistry of d-block elements:
Characteristics of d-block
elements with special reference to electronic configuration, variable valence,
magnetic properties, catalytic properties and ability to form complexes.
Stability of various oxidation states.
2. Chemistry of f-block elements:
Chemistry of lanthanides -
electronic structure, oxidation states, lanthanide contraction, consequences of
lanthanide contraction, magnetic properties. Chemistry of actinides -
electronic configuration, oxidation states, actinide contraction, comparison of
lanthanides and actinides.
3. Theories of bonding in metals:
Valence bond
theory andFree electron theory, explanation of thermal and electrical
conductivity of metals based on these theories, Band theory- formation of
bands, explanation of conductors, semiconductors and insulators.
UNIT-III :
Solidstate
Symmetry in
crystals. Law of constancy of interfacial angles. The law of rationality of
indices. The law of symmetry. Miller indices, Definition of lattice point,
space lattice, unit cell. Bravais lattices and crystal systems. X-ray
diffraction and crystal structure. Bragg's law. Powder method. Defects in
crystals. Stoichiometric and non-stoichiometric defects.
UNIT-IV
1. Gaseous state
van der Waal's
equation of state. Andrew's isotherms of carbon dioxide, continuity of state.
Critical phenomena. Relationship between critical constants and vander Waal's
constants. Lawof corresponding states. Joule- Thomson effect. Inversion
temperature.
2.Liquid state
Liquid
crystals,mesomorphicstate. Differences between liquid crystal and solid/liquid.
Classification of liquid crystals into Smectic and Nematic. Application of
liquid crystals as LCD devices.
UNIT-V
Solutions, Ionic
equilibrium& dilute solutions
1. Solutions
Azeotropes-[HCl-H2O
system and] ethanol-water system. Partially miscible liquids- Critical solution
temperature (CST) phenol-water system., Effect of impurity on consulate
temperature. Immiscible liquids and steam distillation.Nernst distribution
law.[ Calculation of the partition coefficient]. Applications of distribution
law.
2. Ionic
equilibrium
Ionic
product, common ion effect, solubility and solubility product [Calculations
based on solubility product]..
3. Dilute
solutions
Colligative
properties- RLVP, Osmotic pressure, Elevation in boiling point and depression
in freezing point. Experimental methods for the determination of molar mass of
a non-volatile solute using osmotic pressure by Berkley and Hartley’s
method [Elevation in boing point and
depression in freezing point]. Abnormal colligative properties. Van't Hoff
factor
Deleted
topics in Unit V .
1. Solutions: [HCl-H2O system , [ Calculation of the partition
coefficient]
2.Ionic equilibrium: [ Calculation of the partition coefficient]
3. Dilute solutions : Elevation in boing point and depression in freezing point Elevation in boing point and depression in freezing point
Chemistry
PAPER 1: Inorganic &Physical Chemistry
Important Questions , Mid Examination and Public Examination Papers
| Important Questions |  |
| Mid Examination 1 | |
| Mid Examination 2 | |
| Public Examination Papers 2020 | |
| Public Examination Papers 2021 | |
| Public Examination Papers 2022 | |
Chemistry
Paper- I : Inorganic
&Physical Chemistry
SYLLABUS
UNIT –I : Chemistry of p-block elements
Group 13: Preparation & structure of Diborane, Borazine
Group 14: Preparation, classification and uses of silicones
Group 15: Preparation & structures of Phosphonitrilic halides {(PNCl2)n
where n=3, 4
Group 16: Oxides and Oxoacids of Sulphur (structures only)
Group 17: Pseudohalogens, Structures of Interhalogen compounds.
1. Chemistry of d-block elements:
Characteristics of d-block
elements with special reference to electronic configuration, variable valence,
magnetic properties, catalytic properties and ability to form complexes.
Stability of various oxidation states.
2. Chemistry of f-block elements:
Chemistry of lanthanides -
electronic structure, oxidation states, lanthanide contraction, consequences of
lanthanide contraction, magnetic properties. Chemistry of actinides -
electronic configuration, oxidation states, actinide contraction, comparison of
lanthanides and actinides.
3. Theories of bonding in metals:
Valence bond
theory andFree electron theory, explanation of thermal and electrical
conductivity of metals based on these theories, Band theory- formation of
bands, explanation of conductors, semiconductors and insulators.
UNIT-III :
Solidstate
Symmetry in
crystals. Law of constancy of interfacial angles. The law of rationality of
indices. The law of symmetry. Miller indices, Definition of lattice point,
space lattice, unit cell. Bravais lattices and crystal systems. X-ray
diffraction and crystal structure. Bragg's law. Powder method. Defects in
crystals. Stoichiometric and non-stoichiometric defects.
UNIT-IV
1. Gaseous state
van der Waal's
equation of state. Andrew's isotherms of carbon dioxide, continuity of state.
Critical phenomena. Relationship between critical constants and vander Waal's
constants. Lawof corresponding states. Joule- Thomson effect. Inversion
temperature.
2.Liquid state
Liquid
crystals,mesomorphicstate. Differences between liquid crystal and solid/liquid.
Classification of liquid crystals into Smectic and Nematic. Application of
liquid crystals as LCD devices.
UNIT-V
Solutions, Ionic
equilibrium& dilute solutions
1. Solutions
Azeotropes-[HCl-H2O
system and] ethanol-water system. Partially miscible liquids- Critical solution
temperature (CST) phenol-water system., Effect of impurity on consulate
temperature. Immiscible liquids and steam distillation.Nernst distribution
law.[ Calculation of the partition coefficient]. Applications of distribution
law.
2. Ionic
equilibrium
Ionic
product, common ion effect, solubility and solubility product [Calculations
based on solubility product]..
3. Dilute
solutions
Colligative
properties- RLVP, Osmotic pressure, Elevation in boiling point and depression
in freezing point. Experimental methods for the determination of molar mass of
a non-volatile solute using osmotic pressure by Berkley and Hartley’s
method [Elevation in boing point and
depression in freezing point]. Abnormal colligative properties. Van't Hoff
factor
Deleted
topics in Unit V .
1. Solutions: [HCl-H2O system , [ Calculation of the partition
coefficient]
2.Ionic equilibrium: [ Calculation of the partition coefficient]
3. Dilute solutions : Elevation in boing point and depression in freezing point Elevation in boing point and depression in freezing point
Chemistry
PAPER 1: Inorganic &Physical Chemistry
Important Questions , Mid Examination and Public Examination Papers
| Important Questions | |
| Mid Examination 1 | |
| Mid Examination 2 | |
| Public Examination Papers 2020 | |
| Public Examination Papers 2021 | |
| Public Examination Papers 2022 | |
